Estructura y propiedades térmicas de oleogeles a base de cera de abejas con diferentes tipos de aceites vegetales

Beeswax-based oleogels with different types of vegetable oil, including camellia oil (CO), soybean oil (SO), sunflower oil (SFO), or flaxseed oil (FO), were prepared and their structure and thermal properties were evaluated. The critical concentration of oleogel obtained from each of CO, SO, and SFO at 25 °C was 3% (w/w), and that from FO was 4%. Thermal measurements revealed similar thermodynamic curves for oleogels in different lipid phases. X-Ray diffraction showed orthorhombic perpendicular subcell packing and characteristic peaks of the β’ form. Furthermore, a morphology analysis of the crystals showed that they were needle shaped. Fourier transform-infrared spectra revealed that beeswax-based oleogels were formed via non-covalent bonds and may be stabilized with physical entanglements. The oleogels showed oil type-dependent oxidative abilities, but they were all stable and showed no obvious changes in peroxide value during 90 days of storage at 5 °C.Se prepararon oleogeles a base de cera de abejas con diferentes tipos de aceite vegetal, incluido el aceite de camelia (CO), de soja (SO), girasol (SFO) y linaza (FO), y se evaluaron la estructura y las propiedades térmicas. La concentración crítica de oleogel obtenida de cada uno de los aceites de CO, SO y SFO a 25 °C fue del 3% (p / p), y la del FO fue del 4%. Las medidas térmicas dieron curvas termodinámicas similares para los oleogeles en diferentes fases lipídicas. La difracción de rayos X mostró un empaquetamiento subcelular perpendicular ortorrómbico y picos característicos de la forma β’. Además, el análisis de la morfología de los cristales mostró que tenían forma de aguja. Los espectros infrarrojos de transformada de Fourier revelaron que los oleogeles basados en cera de abejas se formaron a través de enlaces no covalentes y pueden estabilizarse con enlaces físicos. Los oleogeles mostraron capacidades oxidativas dependientes del tipo de aceite, pero todos eran estables y no tuvieron cambios obvios en el valor del peróxido durante 90 días de almacenamiento a 5 °C

Parton Interpretation and Twist-4 Parton Distributions

Through explicit examples we show that twist-4 parton distributions have no parton interpretation in the sense that parton or partons inside a hadron can carry the momentum fraction $x$ of the hadron with $x >1$ or $x<-1$. The studied twist-4 parton distributions of collinear factoization are power-divergent for $\vert x\vert >1$. The corresponding transverse momentum dependent parton distributions have also no parton interpretation. They are finite. The implications of our results are discussed.Comment: 11 pages, 3 figure

PEDS: Passivity enforcement for descriptor systems via Hamiltonian- symplectic matrix pencil perturbation

Passivity is a crucial property of macromodels to guarantee stable global (interconnected) simulation. However, weakly nonpassive models may be generated for passive circuits and systems in various contexts, such as data fitting, model order reduction (MOR) and electromagnetic (EM) macromodeling. Therefore, a post-processing passivity enforcement algorithm is desired. Most existing algorithms are designed to handle poleresidue models. The few algorithms for state space models only handle regular systems (RSs) with a nonsingular D+D T term. To the authors' best knowledge, no algorithm has been proposed to enforce passivity for more general descriptor systems (DSs) and state space models with singular D + D T terms. In this paper, a new post-processing passivity enforcement algorithm based on perturbation of Hamiltonian-symplectic matrix pencil, PEDS, is proposed. PEDS, for the first time, can enforce passivity for DSs. It can also handle all kinds of state space models (both RSs and DSs) with singular D + D T terms. Moreover, a criterion to control the error of perturbation is devised, with which the optimal passive models with the best accuracy can be obtained. Numerical examples then verify that PEDS is efficient, robust and relatively cheap for passivity enforcement of DSs with mild passivity violations. ©2010 IEEE.published_or_final_versionThe IEEE/ACM International Conference on Computer-Aided Design (ICCAD 2010), San Jose, CA., 7-11 November 2010. In Proceedings of ICCAD, 2010, p. 800-80

Etanercept Inhibits Pro-inflammatory Cytokines Expression in Titanium Particle-Stimulated Peritoneal Macrophages

Purpose: To investigate the inhibitory role of Etanercept in pro-inflammatory cytokines such as TNF-α, IL-1β and IL-6 production in titanium (Ti) particle stimulated macrophages.Methods: Peritoneal macrophages were stimulated with 1 × 109 Ti particles and treated simultaneously with or without 10, 100, or 1000 ng/mL Etanercept. The levels of TNF-α, IL-1β and IL-6 in the culture supernatants were measured using ELISA.Results: Titanium particles could stimulate TNF-α, IL-1β and IL-6 secretion in peritoneal macrophages. Etanercept inhibited Ti particle-induced TNF-α release by 29.7 % at 10 ng/ml (19.19 ± 4.72 pg/mL, p &lt; 0.01), 49.3 % at 100 ng/mL (13.83 ± 3.72 pg/ml, p &lt; 0.01) and 60.4 % at 1000 ng/mL (10.82 ± 3.87 pg/mL, p &lt; 0.001), IL-1β release by 5.23 % at 10 ng/mL (34.79 ± 7.83 pg/mL, p &gt; 0.05), 21.06 % at 100 ng/mL (28.98 ± 4.81 pg/mL, p &lt; 0.01) and 29.83 % at 1000 ng/mL (25.76 ± 5.23 pg/ml, p &lt; 0.001), and IL-6 release by 38.69 % at 10 ng/mL (256.8 ± 99.56 pg/mL, p &lt; 0.01), by 42.13 % at 100 ng/mL (242.4 ± 33.26 pg/mL, p &lt; 0.01) and 53.4 % at 1000 ng/ml (195.2 ± 48.82 pg/mL, p &lt; 0.001).Conclusion: Etanercept has potent ability to prevent wear debris–induced osteolysis and may be valuable as a therapeutic agent for the treatment of prosthetic loosening in humans.Keywords: Etanercept; titanium particle; proinflammatory cytokines; peritoneal macrophage

Passivity enforcement for descriptor systems via matrix pencil perturbation

Passivity is an important property of circuits and systems to guarantee stable global simulation. Nonetheless, nonpassive models may result from passive underlying structures due to numerical or measurement error/inaccuracy. A postprocessing passivity enforcement algorithm is therefore desirable to perturb the model to be passive under a controlled error. However, previous literature only reports such passivity enforcement algorithms for pole-residue models and regular systems (RSs). In this paper, passivity enforcement algorithms for descriptor systems (DSs, a superset of RSs) with possibly singular direct term (specifically, D+D T or I-DD T) are proposed. The proposed algorithms cover all kinds of state-space models (RSs or DSs, with direct terms being singular or nonsingular, in the immittance or scattering representation) and thus have a much wider application scope than existing algorithms. The passivity enforcement is reduced to two standard optimization problems that can be solved efficiently. The objective functions in both optimization problems are the error functions, hence perturbed models with adequate accuracy can be obtained. Numerical examples then verify the efficiency and robustness of the proposed algorithms. © 2012 IEEE.published_or_final_versio